Synthesis of an anionic Au(I) hydroamination precatalyst supported by charged hydrido-carboranyl phosphine ligands

Jack F. Kleinsasser,Sarah E. Lee,Christopher A. Lugo,Varun Tej,Scott G. McArthur,Vincent Lavallo

Polyhedron（2018）

引用 6|浏览11

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摘要

An anionic Au(I) complex supported by two charged carboranyl phosphines is reported. Its catalytic activity for the hydroamination of alkynes is investigated and compared to the most active known system.

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关键词

Gold catalysis,Hydroamination,Carborane anion,Carborane ligand,Electrostatic effects

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