The necessary and sufficient conditions for chemical equilibrium

E. A. Smolenskii,A. N. Ryzhov, I. V. Chuvaeva,L. K. Maslova,A. L. Lapidus

Russian Chemical Bulletin（2018）

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摘要

The article concerns a widely accepted but incorrect concept of conditions for chemical equilibrium. The authors present a mathematically rigorous derivation of the necessary and sufficient conditions for chemical equilibrium of systems of arbitrary complexity.

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关键词

principle of detailed balancing, formal kinetics, chemical equilibrium

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