DISPERSION OF NANOCLAY IN 1,4-POLYBUTADIENE

Two approaches to obtaining better dispersion of organo-modified nanoclay in high-molecular weight polybutadiene were assessed: (1) chemical modification of the polymer to increase its affinity for the silicate layers and (2) increasing the stretching component of the flow field used to mix the materials. As expected, the degree of dispersion, that is, the extent of intercalation of the polymer into the clay galleries and amount of exfoliation of the clay layers, increased with closer matching of the respective solubility parameters of the components. The efficiency of mechanical mixing was greater for flow fields dominated by stretching (extensional flow); less mix energy had to be expended to achieve a given level of reinforcement. However, without sufficient affinity of the polymer for the clay, complete exfoliation could not be obtained solely by mixing. Nevertheless, incomplete dispersion of the nanoclay still yields more than 40-fold increases in viscosity with 5% clay.