A metal-catalyst-free oxidative coupling of anilines to aromatic azo compounds in water using bleach

Tetrahedron Letters(2018)

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摘要
•Synthesis of symmetrical and unsymmetrical aromatic azo compounds from anilines using a straightforward protocol in water.•Low-cost reagents (Bleach and HCl).•Low-cost energy input (room temperature).•Gram-scale reaction with no safety concerns.
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关键词
Anilines,Aromatic azo compounds,Oxidative coupling,Sodium hypochlorite,In water
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