Structural and spectroscopic investigations of redox active seven coordinate luminescent lanthanide complexes

Inorganica Chimica Acta(2018)

Cited 18|Views25
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Abstract
•Tris(phenolato) lanthanide complexes (Gd, Tb, Yb, Lu) were crystallized.•Oxidation affords phenoxyl radical species.•The tris(phenolato) terbium and ytterbium complexes are luminescent.•The luminescence is quenched upon oxidation.
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Key words
Phenoxyl,Radical,Redox noninnocent ligand,Lanthanides,Luminescence
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