Palladium(0)-Catalyzed Si-Si Bond Insertion by the Terminal Nitrogen of Diazo Compounds
CHINESE JOURNAL OF CHEMISTRY（2018）
Abstract
The palladium(0)-catalyzed nitrogen insertion into cyclic SiSi bonds has been realized by using N-tosylhydrazones/diazo compounds as the nitrogen source. The palladium(II) nitrene formation and subsequent migratory insertion process are proposed as the key steps for this reaction.
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Key words
insertion,diazo compounds,SiSi bond,palladium catalysts,palladium(II) nitrene,carbenes
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