Importance of the orthogonal structure between porphyrin and aniline moieties on the pH-activatable porphyrin derivative for photodynamic therapy

Hiroaki Horiuchi,Atsuki Hirabara,Tetsuo Okutsu

Journal of Photochemistry and Photobiology A: Chemistry（2018）

引用 9|浏览15

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摘要

•Intramolecular orthogonal structure is important for the ON/OFF switching.•The suppressed rotation improves maximum quantum yield.•pH Region of the ON/OFF switching was improved by using diethylamino group.

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关键词

Photosensitizer,Singlet oxygen,pH,ON/OFF switching,Intramolecular orthogonality

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