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Reusable rhodium catalyst for the selective transvinylation of sp 2 -C linked carboxylic acid

Ruihang Jiang,Zhangpei Chen,Kun Zhan,Lei Liu,Junjie Zhou,Yongjian Ai, Shuang Li,Hongjie Bao,Zenan Hu,Li Qi,Jingting Wang,Hong-bin Sun

Tetrahedron Letters（2018）

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Abstract
•A ligand-free and air & water tolerance rhodium catalyst for transfer vinylation.•This protocol works selectively for sp2-C-linked carboxylic acid.•Both carbonyl and chloride contribute to catalytic activity.•Reusable ability for transvinylation.
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Key words
Rhodium chloride,Transvinylation,Vinyl benzoate,Vinyl ester,Transesterification
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