Evaluation of physical and chemical adsorption using electrochemical noise technique for methylene blue on mild steel
The Journal of Chemical Thermodynamics(2018)
Abstract
•Methylene blue (MB) shows high inhibition efficiency in 1 M HCl.•Adsorption mechanism changes from physical to chemical with increasing MB concentration.•New parameter of pitting active energy CAE was proposed.•CAE initially increases when follows physical adsorption, then decreases when chemisorption mechanism was obeyed.
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Key words
Mild steel,Adsorption,Methylene blue,Electrochemical noise
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