Use and Recyclability of Scandium Tris[bis(perfluorooctylsulfonyl)amide] As A Lewis Acid Promoter for Glycosidation Reactions

Takashi Yamanoi,Ryo Inoue,Yoshiki Oda,Akihiro Yoshida

LETTERS IN ORGANIC CHEMISTRY（2018）

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摘要

In this study, the application of scandium tris[bis(perfluorooctylsulfonyl)amide] as a catalyst in glycosidation reactions was investigated. Besides being a versatile Lewis acid promoter for such reactions, the studied complex could be easily recovered from the reaction mixtures with sufficient activity to repeatedly catalyze the glycosidation reactions.

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关键词

Glycosidation,Lewis acid,scandium tris[bis(perfluorooctylsulfonyl)amide],in situ reaction,recycle reaction,catalytic reaction,synthesis,glycoside

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