Enantioselective metal-free reduction of ketones by a user-friendly silane with a reusable chiral additive
Tetrahedron Letters(2018)
摘要
•Asymmetric reduction of ketones using easy-to-handle and inexpensive silatrane.•Commercially available 1,2-aminoalcohols served to induce chirality (ees up to 86%).•Chiral additives are used stoichiometrically, but recyclable (with full activity).
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关键词
Hydrosilylation,Asymmetric ketone reduction,Synthesis of chiral alcohols
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