Synthesis of bay-triaminosubstituted perylenediimides

D. Gutiérrez-Moreno,Ángela Sastre-Santos,Fernando Fernández-Lázaro

Organic Chemistry Frontiers（2018）

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摘要

A mild fluoride-mediated reaction opens the way to the synthesis of the previously unknown bay-triaminosubstituted and bay-tri(heteroar-N-yl)substituted perylenediimides (PDIs). TriaminoPDIs show bathochromically shifted absorptions reaching near-infrared with increased extinction coefficients when compared to the diamino ones.

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