Efficient resolution of (R,S)-1-(1-naphthyl)ethylamine by Candida antarctica lipase B in ionic liquids
Molecular Catalysis(2018)
Abstract
•The ionic liquids were firstly applied for the enzymatic resolution of (R,S)-1-(1-naphthyl)ethylamine.•Great improvement in enantiomeric excess of R-type product was obtained in IL [C6mim][Tf2N].•Vinyl n-octanoate suppressed the non-enzymatic reaction and excellent value of enantiomeric excess of R-type product was achieved.
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Key words
(R,S)-NEA,CALB,ILs,[Tf2N]−,[BF4]−,[PF6]−,[Cnmim]+,CD
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