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Aerobic oxidations with N -hydroxyphthalimide in trifluoroacetic acid

Pavel A. Gunchenko, Jing Li,Bifu Liu,Hongyan Chen,Alexander E. Pashenko,Vladyslav V. Bakhonsky,Tatyana S. Zhuk,Andrey A. Fokin

Molecular Catalysis（2018）

Cited 23|Views45
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Abstract
•Effective oxidation of toluene to benzaldehyde at room temperature in the TFA/NHPI/NaNO2/O2 system is suggested.•Oxidation of cyclohexane in TFA/NHPI/HNO3/O2 at 50 °C gave adipic acid in 45% preparative yield.•Oxidation of 3-oxadiamantane in TFA/NHPI/HNO3/O2 at 50 °C gave previously inaccessible 9-hydroxy-3-oxadiamantane.
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Key words
Oxidation,Metal free,Toluene,Benzaldehyde,Cyclohexane,Adipic acid,3-oxadiamantane,NHPI
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