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Complexation of dichloro(ethylenediamine)palladium(II) with 1-hydroxyethylidene-1,1-diphosphonic acid

O.M. Kozachkova,N.V. Tsaryk,V.I. Pekhnyo,V.V. Trachevskyi,A.B. Rozhenko,V.V. Dyakonenko

Inorganica Chimica Acta（2018）

Cited 9|Views8
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Abstract
Complexation of [Pd(en)Cl2] with 1-hydroxyethylidene-1,1-diphosphonic acid (L) was studied by pH-potentiometry, UV–Vis and NMR spectroscopy. The binuclear complex {[Pd(en)]2L} was isolated and its structure was determined by single-crystal X-ray diffraction and 31P NMR spectroscopy.
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Key words
Diphosphonic acid,Dichloro(ethylenediamine)palladium(II),Formation constants,X-ray diffraction
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