Nanostructured membranes containing UiO-66 (Zr) and MIL-101 (Cr) for O 2 /N 2 and CO 2 /N 2 separation

Maíra Andrade Rodrigues, Jéssica de Souza Ribeiro, Elisângela S. Costa,Jussara De Miranda,Helen Conceição Ferraz

Separation and Purification Technology(2018)

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Abstract
•UiO-66 (Zr) and MIL-101 (Cr) were successfully synthesized.•Photomicrographs reveal a good compatibility between particles and polymer matrix.•MMM containing UiO-66 (Zr) present an increasing of 36% in O2/N2 selectivity.•MIL-101 (Cr) dispersed in MMM caused a significant increase in CO2 permeability.•Selectivity of MMM containing MIL-101 (Cr) to CO2/N2 separation was not affected.
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Key words
Metal-organic framework,Mixed matrix membranes,Oxygen,Carbon dioxide,Zirconium,Chromium
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