Boron trifluoride facilitated transesterification of dioxaborolanes
Tetrahedron Letters（2017）
Abstract
•Catechol boronate esters can be synthesized from pinacolyl boronate esters.•The transesterification is facilitated by boron trifluoride.•The process is assisted by the concomitant pinacol rearrangement.
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Key words
Boronic acids,Dioxaborolanes,Boronate esterification,Boron trifluoride,Pinacol rearrangement
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