Catalytic Asymmetric Synthesis of Unnatural Amino Acids
Synfacts(2011)
Abstract
The authors report the asymmetric synthesis of unnatural amino acids through asymmetric allylic substitution followed by a cross-metathesis reaction. The sequential catalytic systems using Cu, Ru and Ir are all well controlled with high stereoselectivities and, thus, the method provides stereodivergent access to unnatural amino acids.
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Key words
unnatural amino acids,amino acids,synthesis
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