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Synthesis of dehydroindolizidine-type poison-frog alkaloids via Michael-type conjugate addition

De-Jun Zhou,Xue-Yan Li, Dong Li,Zhong-Shuai Guo, Qin-Ling Zhang,Hong-Yan Bie,Zheng-Guo Cui

JOURNAL OF CHEMICAL RESEARCH（2017）

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Abstract
A concise stereoselective synthesis of proposed dehydroindolizidine-alkaloids of types 179 and 207E(1) was accomplished via Michael-type conjugate addition. A comparison of natural 207E and synthesised compound 207E on GC-FTIR revealed the double bond of natural 207E is most likely at the 7,8-position.
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dehydroindolizidine,Michael-type conjugate addition
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