Multinuclear rare-earth metal complexes supported by chalcogen-based 1,2,3-triazole

Ana Cristina García-Álvarez,Erandi Bernabé-Pablo,Joaquín Barroso-Flores,Vojtech Jancik,Diego Martínez-Otero,T. Jesús Morales-Juárez,Mónica Moya-Cabrera

Polyhedron（2017）

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摘要

The reaction of MCp3 with the hetero donor-chelating ligand 4,5-bis(diphenylselenophosphoranyl)-1,2,3-triazole afforded the trinuclear complexes (M=Y, Nd, Sm, Gd). X-ray diffraction studies revealed that these compounds possess a trinuclear M3(μ3O) core exhibiting short M–Se contacts.

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关键词

Rare-earth metals,Selenium,1,2,3-Triazoles,X-ray,DFT

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