Synthesis of a versatile pentacyclic building block for organic electronics
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY(2017)
摘要
A new pentacyclic building block, benzodibenzofuranquinone (BDBFQ), is synthesized in a single step from the inexpensive and readily available feedstocks chloranil and 3bromophenol. This versatile repeat unit is incorporated into a series of conjugated materials as either the redox active quinone form or as an electron-rich dialkylated benzodibenzofuran (BDBF) unit. To illustrate the performance that can be obtained from these systems, optical and electrochemical properties were studied via UV-vis-NIR spectroscopy and cyclic voltammetry. Thin-film morphology was characterized via grazing incidence wide-angle X-ray scattering with thin-film fieldeffect transistor measurements further demonstrating the utility of this system. (C) 2017 Wiley Periodicals, Inc.
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关键词
conjugated polymers,copolymers,organic electronics,polycyclic building blocks,redox polymers
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