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Phosphonium-phosphates/thiophosphates: Ionic liquids or liquid ion pairs? NMR spectroscopic classification

Sujit Mondal,Tanmay Mandal,Meeta Sharma,Ravindra Kumar,Ajay Kumar Arora,Veena Bansal,Jayaraj Christopher,Gurpreet Singh Kapur

Tetrahedron Letters（2017）

Cited 5|Views9
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Abstract
Ion association in chloroform solution increases in increasing alkyl chain length (R) in the phosphonium moiety and decreases going from diaryl phosphate (PP) to diaryl thiophosphate (PTP).
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Key words
NMR,DOSY NMR,Ionic liquid,Ion association,Liquid ion pair,Phosphonium phosphate,Phosphonium thiophosphate
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