CuF2 as Reversible Cathode for Fluoride Ion Batteries
ADVANCED FUNCTIONAL MATERIALS(2017)
摘要
In the search for novel battery systems with high energy density and low cost, fluoride ion batteries have recently emerged as a further option to store electricity with very high volumetric energy densities. Among metal fluorides, CuF2 is an intriguing candidate for cathode materials due to its high specific capacity and high theoretical conversion potential. Here, the reversibility of CuF2 as a cathode material in the fluoride ion battery system employing a high F-conducting tysonite-type La0.9Ba0.1F2.9 as an electrolyte and a metallic La as an anode is investigated. For the first time, the reversible conversion mechanism of CuF2 with the corresponding variation in fluorine content is reported on the basis of X-ray photoelectron spectroscopy measurements and cathode/electrolyte interfacial studies by transmission electron microscopy. Investigation of the anode/electrolyte interface reveals structural variation upon cycling with the formation of intermediate layers consisting of i) hexagonal LaF3 and monoclinic La2O3 phases in the pristine interface; ii) two main phases of distorted orthorhombic LaF3 and monoclinic La2O3 after discharging; and iii) a tetragonal lanthanum oxyfluoride (LaOF) phase after charging. The fading mechanism of the cell capacity upon cycling can be explained by Cu diffusion into the electrolyte and side reactions due to the formation of the LaOF compound.
更多查看译文
关键词
copper fluoride CuF2,electrode/electrolyte interfaces,electron microscopy,fluoride ion conductors,solid state batteries
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要