Parameters Affecting Adsorption and Photocatalytic Degradation Behavior of Gentian Violet under UV Irradiation with Several Kinds of TiO2 as a Photocatalyst

The photocatalytic decolorization of Gentian violet (GV) from an aqueous solution was studied by focusing on comparison of the photoactivity of different type of TiO2 catalyst. The process was carried out under a variety of conditions. The efficiency of P25-Degussa and PC50-Millennium photocatalysts were compared. The effect of different parameters such as pH, initial dye concentration, catalyst loading and the presence of some anions on both adsorption in the absence of light and the degradation under UV irradiation have been studied. 365 nm UV-A lamp was employed as irradiation source. The kinetic study showed that no correlation was observed between the adsorption capacity of the catalyst and its photoactivity, despite of this the effect of various parameters on adsorption and photocatalytic kinetic behavior was practically similar on various catalysts. The photocatalytic degradation of GV followed first-order reaction kinetics and the higher adsorption and photocatalytic degradation were obtained at the alkaline medium (pH = 10 for P25 and pH = 8 for PC50). However, the reaction at the acidic medium was gradually delayed due to the effect of charge repulsion. The presence of some anions (Cl-, SO42-, NO3-) in the medium at higher concentration was found to reduce the adsorption and to inhibit the degradation.