Influence of temperature on the growth and surface morphology of Fe3+ poisoned KDP crystals

A series of potassium dihydrogen phosphate (KDP) crystals and Fe3+ doped KDP crystals were grown at different temperatures and at the same supersaturation value of 0.02. The prismatic face growth rates of the KDP crystals were measured using a laser polarization interference system. The surface morphologies of the growth steps on the {100} face were comparatively studied using an atomic force microscope systematically. The results showed that the bunching of steps was related to the supersaturation interval in which it was located, and approached the supersaturation dead zone of sigma(d) in which the bunching and the slope of the steps were high. The supersaturation dead zone sigma(d) and linear zone sigma* decreased with rising temperature. Varying the temperature caused considerable changes in the growth speed, step morphology and step motion speed. For the crystal grown in a doped solution, the bunching and slope of the steps reached a maximum value at around 45 degrees C. It was interesting that the crystal growth rate in the doped solution was higher than that in the undoped solution at around 65 degrees C and 75 degrees C, the bunching of the steps was reduced and the width of the steps widened significantly. At the same supersaturation, the growth rate increased with rising temperature and the steps became straight.