Synthesis And Crystal Structure Of Cadmium(Ii) Dichloroaquasalicylidenesemicarbazone
CHEMISTRY & CHEMICAL TECHNOLOGY(2016)
摘要
Cadmium(II) complex with salicyl aldehyde semicarbozone (H2L) has been synthesized. Based on elemental analysis and IR spectroscopy its composition [Cd.H2L.H2O.Cl-2] - has been established. The complex crystal structure has been examined using XRD analysis. The coordination polyhedron of cadmium atom is a distorted octahedron, where two cis- positions are occupied by oxygen atoms of water molecule and carbamide fragment of H2L molecule, other positions are occupied by chlorine atoms. At the same time two edges of octahedron are combined with adjoined octahedrons and form endless zigzag chains of octahedrons in the structure along the crystallographic axis. H2L molecule is a planar one due to the presence of intramolecular hydrogen bond.
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关键词
cadmium, salicylidenesemicarbazone, XRD
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