Copper(II) perchlorate complexes with N-arylalkyliminodiacetamide ligands: X-ray structural, vibrational spectroscopic, DFT and thermogravimetric studies

Neven Smrečki,Vladimir Stilinović,Ozren Jović,Boris-Marko Kukovec,Zora Popović

Inorganica Chimica Acta（2017）

引用 7|浏览2

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摘要

Copper(II) perchlorate complexes with N-arylalkyliminodiacetamide derivatives (Bnimda, Peimda, Ppimda; Bn=benzyl, Pe=2-phenylethyl; Pp=3-phenylprop-1-yl), namely [Cu(Bnimda)2](ClO4)2 (1), [Cu(Peimda)2](ClO4)2 (2) and [Cu(Ppimda)2](ClO4)2·2H2O (3) were characterized by IR spectroscopy and studied by DFT. Crystal structures were determined by X-ray structural analysis.

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关键词

Copper(II) complexes,Iminodiacetamide,Crystal structure,Hydrogen bond motifs,IR spectroscopy,DFT geometry and vibrational calculation

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