Synthesis of retinoid analogues of juvenile hormones
APPLIED ORGANOMETALLIC CHEMISTRY(2017)
摘要
As part of a collaborative research project aimed at designing new chemicals active on mosquito larvae, we sought accessible raw materials and an efficient synthesis method for preparing large amounts of active substances. For this we selected retinoic acid, which has functionality close to that of juvenile hormones. From this molecule we developed ester and trifluoromethyl ketone synthesis that was fast and led to good yields.
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关键词
juvenile hormones,larvicides,Mitsunobu reaction,retinoic acid,Ruppert reagent
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