Copper-Catalyzed Stereodefined Construction of Acrylic Acid Derivatives from Terminal Alkynes via CO2 Insertion

Kenta Kuge,Ying Luo,Yuki Fujita,Yasuyuki Mori,Gen Onodera,Masanari Kimura

Organic Letters（2017）

引用 26|浏览2

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摘要

IPrCuCl catalyzes the CO2 insertion reaction undergone by a dialkylvinylborane intermediate derived from alkynyltrialkylborate by a 1,2-alkyl group migration to afford α-alkyl acrylic acids with excellent regio- and stereoselectivities.

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关键词

acrylic acid derivatives,terminal alkynes,copper-catalyzed

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