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The role of chemisorbed water in formation and stabilization of active sites on Pd/Alumina oxidation catalysts

Aleksey A. Vedyagin,Alexander M. Volodin,Roman M. Kenzhin,Vladimir O. Stoyanovskii,Vladimir A. Rogov,V. V. Kriventsov,Ilya V. Mishakov

Catalysis Today（2018）

Cited 35|Views18
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Abstract
•A series of Pd/Al2O3 catalysts with palladium loadings of 0.125–4wt.% was studied.•Isolated Pd2+ ions are responsible for high catalytic activity in CO oxidation.•Donor sites of alumina stipulate the stabilization effect observed.•Chemisorbed water prevents deactivation of palladium active sites.
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Key words
CO oxidation,Palladium catalysts,Alumina,Stability,Chemisorbed water
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