Influence of single-walled carbon nanotubes enriched in semiconducting and metallic tubes on the electropolymerization of tetrabromo ortho-xylene: Insights on the synthesis mechanism of poly(ortho-phenylenevinylene)

European Polymer Journal(2017)

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Abstract
•Spectroelectrochemical properties of poly(ortho-phenylenevinylene) (POPV) are shown.•Covalently functionalization of S-SWNTs with POPV was proved by IR spectroscopy.•The POPV chains length correspond to 3 and 7–10 repeating units.•POPV luminescence quenching process is induced of SWNTs (14,7), (12,10) and (11,9).
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Key words
Poly(ortho-phenylenevinylene),Single-walled carbon nanotubes,Vibrational properties,Photoluminescence,Cyclic voltammetry
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