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Copper Iodide Mediated Cyanation of Arylboronic Acids and Aryl Iodides with Ethyl (Ethoxymethylene)cyanoacetate as Cyanating Agent

Chaorong Qi,Xiaohan Hu,Haitao He

SYNLETT（2016）

Cited 13|Views2
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Abstract
An efficient copper iodide mediated cyanation of arylboronic acids and aryl iodides with ethyl (ethoxymethylene)cyanoacetate as cyanating agent has been developed. The reaction involves a C(sp(2))-CN bond cleavage and tolerates a wide range of functional groups, affording the corresponding aryl nitriles in moderate to excellent yields.
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Key words
copper,nitriles,transition metals,cleavage,arenes
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