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Comparative transfer hydrogenation performance of homogeneous and heterogeneous ruthenium (II) catalysts derived from a Schiff base ligand

Esin İspir,Ertan Sahin,Mesut İkiz,Arif Aktas

Journal of Organometallic Chemistry（2017）

Cited 6|Views5
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Abstract
A new Schiff base ligand (E)-4-(((pyridin-2-ylmethylene)amino)methyl)phenol (L1H) 1 was synthesized and grafted to solid support successfully. Mononuclear Ru(II) complex 2, its solid supported analogue 4 and heterogeneous complex 5 were synthesized with [RuCl2(p-cymene)]2 and RuCl2(PPh3)dppb.
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Key words
Ru(II) complex,Schiff base,Transfer hydrogenation,Heterogeneous catalyst
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