Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying.

Javier D. Fuhr,Maarten W. van der Meijden,Lucila J. Cristina,Luis Rodriguez,Richard M. Kellogg,J. Esteban Gayone,Hugo Ascolani,Magalí Lingenfelder

CHEMICAL COMMUNICATIONS（2017）

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摘要

The chiral expression of a molecule on a surface is driven from a random solid solution on Cu(100) to a racemic crystal on a Sn/Cu(100) alloy. Density functional theory simulations reveal how the growth of the racemate is influenced by the underlying surface.

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