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Peculiarities of crystallization in the multiblock copolymers of norbornene and cyclooctene

Georgiy A. Shandryuk,Yulia I. Denisova,M.L. Gringolts,L. B. Krentsel,Arkadiy D. Litmanovich,Eugene Sh. Finkelshtein,Yaroslav V. Kudryavtsev

European Polymer Journal（2017）

Cited 21|Views13
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Abstract
•Multiblock NB-COE copolymers were synthesized by cross-metathesis.•SSA thermal fractionation by DSC was carried out.•Degree of crystallinity, Tm, and mean crystallite size decrease with the conversion.•Distribution of crystallite size differs from that in PCOE and PCOE/PNB blend.•Annealing above Tm gives rise to a high-temperature endotherm.
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Key words
Multiblock copolymers,Crystallinity,Degree of blockiness,Thermal fractionation,DSC
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