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The role of intermolecular interactions in polyaniline/polyamide-6,6 pressure-sensitive blends studied by DFT and 1H NMR

Eluise S. Lopes,Eloilson Domingos,Rodrigo S. Neves,Wanderson Romão,Kátia R. de Souza,R. Valaski,Braulio S. Archanjo,Fernando G. Souza,Alexander M. Silva,Alexei Kuznetsov,Joyce R. Araujo

European Polymer Journal（2016）

Cited 20|Views12
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Abstract
•Pressure sensitivity of 25%MPa−1 was achieved by blending PAni with PA-6,6 at weight ratio of 11:1.•H-bonding between PAni and PA-6,6 may provide desirable miscibility level in the two amorphous phases.•Free energy of mixing in the PA-6,6/PAni polymer blend, calculated by DFT, is −5.3kcalmol−1.
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Key words
Polyaniline,Polyamide-6,6,Pressure sensor,X-ray photoelectron spectroscopy,1H Nuclear Magnetic Resonance,DFT calculations
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