Steady Flow of Gas and Decomposing Particles in a Vertical Feed Tube for Applications in Biomass Pyrolysis

Using the approach of interacting and interpenetrating continua, a one-dimensional model is developed for the gravity-driven flow of particles and gas through a vertical standpipe. The gas and particle phases exchange momentum through the drag force, and mass is exchanged between the phases as the particles decompose to gaseous products. On simultaneously integrating the differential equations expressing conservation of mass and momentum for each of the two phases, the theory yields the particle and gas flow rates, the pressure profile, and the particle size and void fraction distributions. Performance diagrams are constructed, and preferred operating conditions are identified that provide steady flow, generate no backpressure, or avoid a transition to moving bed flow or reversed gas flow. The admissible range of operating conditions is found to increase with the particle decomposition rate, and the results may guide the selection of operating conditions in practice. Applications are made to biomass pyrolysis in a catalytic reactor. (c) 2016 American Institute of Chemical Engineers AIChE J, 63: 2318-2334, 2017