Photochemical transformation of the plant activator Acibenzolar-S-methyl in solution

Mohamad Sleiman,Malgorzata Stawinoga, S. Wang, P. De Sainte-Claire,Pascale Goupil,Claire Richard

Journal of Photochemistry and Photobiology A: Chemistry（2017）

引用 10|浏览5

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摘要

•Plant elicitors like BTH are an alternative to conventional pesticides.•BTH absorbs solar light strongly and undergoes fast photolysis in a wide range of solvents.•Loss of N2 by initial cleavage of the S-N bond is highly favored as confirmed by DFT calculations.•Cleavage of the thioester function also takes place.•Numerous photoproducts are formed, in particular those arising from S and ring oxidation.

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关键词

Fate,Bion®,Photolysis,Photoproducts,Radicals

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