Intermediates And Products In The Reaction Of Cinnamaldehyde With (Hoch2)(3)P In Methanol

D. V. Moiseev,B. R. James,A. V. Gushchin,Yu. B. Malysheva

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS（2016）

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摘要

A 1,3-oxaphosphorinan, the product of a 1:1 reaction between cinnamaldehyde and (HOCH2)(3)P, interacts with a second mole of cinnamaldehyde to afford in MeOH an unsymmetrical phosphine oxide as the final product.[GRAPHICS].

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关键词

-Unsaturated aldehydes, tris(hydroxymethyl) phosphine, 1, 3-oxaphosphorinans, phosphine oxides

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