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A novel graphene oxide-polyimide as optical waveguide material: Synthesis and thermo-optic switch properties

Optical Materials(2016)

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摘要
In this work, a novel graphene oxide-polyimide (GOPI) as optical waveguide material was prepared. The structure, mechanical, thermal property and morphology of the GOPI was characterized by using fourier transform infrared, UV–visible spectroscopy, near-infrared spectrum, thermogravimetric analysis, differential scanning calorimetry, scanning electron microscope and transmission electron microscopy. The thermo-optic coefficients (dn/dT) are −9.16 × 10−4 (532 nm), −7.56 × 10−4 (650 nm) and −4.82 × 10−4 (850 nm) °C−1, respectively. Based on the thermo-optic effect of prepared GOPI as waveguide material, a Y-branch with branching angle of 0.143° and Mach-Zehnder thermo-optic switches were designed. Using finite difference beam propagation method (FD-BPM) method, the simulation results such as power consumptions and response times of two different thermo-optic switches were obtained.
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关键词
Optical materials,Polymers,Polyimide,Thermo-optic effect
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