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Biosourced Ligands from Isosorbide for the Ethylation of Aldehydes or Alkynylation of Imines

Khanh‐Duy Huynh,Houssein Ibrahim, Lucie Bouchardy,Chloée Bournaud,Emilie Kolodziej,Martial Toffano,Giang Vo-Thanh

ASIAN JOURNAL OF ORGANIC CHEMISTRY（2016）

Cited 5|Views9
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Abstract
Amino alcohol and diamine ligands were prepared from isosorbide as a chiral renewable resource. The efficiencies of these ligands were evaluated for the metal-cata-lyzed enantioselective ethylation of aldehydes and the alkynylation of aldimines.
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Key words
alkynylation,asymmetric catalysis,isosorbide,ligand design,synthetic methods
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