Diastereoselective Gold(I)-Catalyzed [2+2+2] Cycloaddition of Oxo-1,5-enynes

Pilar Calleja,Michael E. Muratore,Tania Jiménez,Antonio M. Echavarren

SYNTHESIS-STUTTGART（2016）

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摘要

The intramolecular gold(I)-catalyzed [2+2+2] cycloaddition of oxo-1,5-enynes bearing protected homopropargylic alcohols provides access to oxatricyclic adducts with good to excellent diastereoselectivity.

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关键词

gold,enynes,cycloisomerization,cycloaddition,Prins reaction

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