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A Biocatalytic Aza-Achmatowicz Reaction

Elena Fernández-Fueyo,Sabry H. H. Younes,Stefan van Rootselaar,René W. M. Aben,Rokus Renirie,Ron Wever,Dirk Holtmann,Floris P. J. T. Rutjes,Frank Hollmann

ACS Catalysis（2016）

Cited 47|Views18
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Abstract
A catalytic, enzyme-initiated (aza-) Achmatowicz reaction is presented. The involvement of a robust vanadium-dependent peroxidase from Curvularia inaequalis allows the simple use of H2O2 and catalytic amounts of bromide.
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Key words
Achmatowicz reaction,biocatalysis,hypohalogenites,oxidation,peroxidase
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