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A mild, efficient, and selective procedure for the deoxygenation of sulfoxides with the TaCl5/indium system

Byung Woo Yoo, Min Kyung Lee,Cheol Min Yoon

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS（2016）

Cited 11|Views9
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Abstract
The TaCl5/In system was found to be a new reagent for reducing a wide range of structurally diverse sulfoxides to the corresponding sulfides with high yields under mild conditions. This protocol is chemoselective and tolerates several functional groups, such as Br, Cl, OCH3, CHO, and CH = CH2.
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Key words
Deoxygenation,sulfoxide,sulfide,tantalum(V) chloride,indium
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