Hydrogen bonding network-assisted chemiluminescent thermal decomposition of 3-hydroxyphenyl-substituted dioxetanes in crystal
Tetrahedron Letters（2016）
Abstract
•Thermolysis of hydroxyaryl-dioxetane in crystal gives characteristic light.•In nonpolar solution, hydroxyaryl-dioxetane undergoes simple thermolysis.•Hydrogen bonding network assists CT-induced decomposition of dioxetane in crystal.
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Key words
Dioxetane,Chemiluminescence,Hydrogen-bonding,Crystalline state,Thermolysis
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