Synthesis, structure, photo-physical properties and catalytic activities of Zn(II), Cd(II) and Hg(II) complexes of an azinopyridyl ligand
Inorganica Chimica Acta(2016)
摘要
Three new complexes [Zn(L)(NO3)2]n (1), [Cd(L)2(NO3)2]n (2) and [Hg(L)I2]n (3) of an azino pyridyl ligand L, have been synthesized and characterized by single crystal X-ray diffraction studies. In 1, Zn(II) adopts five coordinated distorted trigonal bipyramidal stereochemistry; in 2, Cd(II) is octahedral and in 3, the Hg(II) is distorted tetrahedral. These three complexes are photoluminescent, thermally stable and can also catalyze transesterification reactions.
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关键词
Zn(II), Cd(II), Hg(II) complexes,Coordination polymer,1-D chain and 1-D ribbon,Photophysics,Transesterification reactions
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