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Cation-dependent structural diversity of zinc(II), calcium(II) mono- and binuclear complexes of aryl-imidazo-1,10-phenanthroline derivatives

Yulia Sotnikova,Elena Lukovskaya,Alla Bobylyova,Yury Fedorov,Valentin Novikov,Alexander Peregudov,Aleksander Anisimov,Anthony D’Aléo,Frédéric Fages,Olga Fedorova

Inorganica Chimica Acta（2016）

Cited 2|Views16
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Abstract
Novel azacrown-containing aryl-imidazophenanthroline demonstrates the coordination of Zn(II) with the phenanthroline residue, whereas Ca(II) can bind with both phenanthroline and crown ether centers. This selectivity allows the preparing of a mixed Zn(II)/Ca(II) complex.
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Macrocyclic ligands,Crown-ether,Zinc(II) complex,Calcium(II) complex
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