Thyminato-bridged cyclic tetranuclear rhodium(III) complexes containing a sodium, calcium or lanthanoid ion as a template metal core

Mika Sakate,Ayana Kashima,Haruka Hosoda,Yukinari Sunatsuki,Hiromi Ota,Akira Fuyuhiro,Takayoshi Suzuki

Inorganica Chimica Acta（2016）

引用 9|浏览7

暂无评分

摘要

In the cyclic tetranuclear Cp∗RhIII complexes bridged by thyminato (thym2−) ligands, two bridging modes of thym2− were observed, dependent on the metal ion used as a template: μ3-1κN1:2κ2N3,O2:3κO2 for Na+ and μ3-1κN1:2κ2N3,O4:3κO2 for Ln3+. In the case of a Ca2+-template synthesis both bridging isomers are piled up alternatively in the crystal.

查看译文

关键词

Metallacalix[n]arene,Template synthesis,Heterometallic complexes,Bridging isomers,Crystal structure

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要