Supercritical fluid extraction of triazine herbicides from solid matrices
Chromatographia(1994)
摘要
Several investigations were performed to optimise the extraction of polar triazine herbicides using supercritical fluid extraction from two different solid matrices: C18-silica and soil samples. Supercritical CO2 modified with methanol [10% (V∶V)] at 250 bars and 50°C was required to quantitatively extract Atrazine and 2-Hydroxyatrazine from spiked C18-silica. Extraction of Desisopropyl-desethyl-2-hydroxyatrazine (MET) attained only 52%, even following addition of water to the polar modifier. Extractions of spiked soil samples (20 ppm of each pesticide) were successful at 300 bars and 65°C. A non polar wash improved the recoveries of the three target analytes [i.e. atrazine: 88%; 2-hydroxyatrazine: 96%; MET: 41%]. The extraction parameters employed are discussed in this paper.
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关键词
supercritical fluid extraction
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