Role of water oxidation in the photoreduction of graphene oxide.
CHEMICAL COMMUNICATIONS(2019)
Abstract
By means of a (H2O)-O-18 labeling experiment in combination with mass spectrometry tracking, we studied GO photoreduction. Observation of O-18 labeled O-2 provides direct evidence to confirm that water oxidation occurs during GO photoreduction. In combination with DFT calculations, we propose a mechanism for O-2 and CO2 evolution in the photoreduction of GO.
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Key words
graphene,water oxidation,photoreduction,oxide
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